Comparison of photo- and thermally initiated polymerization-induced self-assembly: a lack of end group fidelity drives the formation of higher order morphologies† †Electronic supplementary information (ESI) available: Additional NMR spectra, SEC, TEM and DLS data as well as histograms for the PEG113–PHPMA400 formulations and MALDI-ToF data for the oligomer study. See DOI: 10.1039/c7py00407a

Probing pattern and dynamics of disulfide bridges using synthesis and NMR of an ion channel blocker peptide toxin with multiple diselenide bonds† †Electronic supplementary information (ESI) available: Details of synthesis and analytical characterization of the Sec-analog of [N17A/F32T]-AnTx mutant including quadrupole ESI and ESI-TOF MS spectra, overlay of 1H-13C HSQC spectra of the double mutant [N17A/F32T]-AnTx and its Sec-analog, scheme and Bruker code of the 77Se-decoupled 1H-77Se CPMG-HSQMBC pulse sequence and comparison of its performance to the classical HMQC method, 1H, 13C, 15N and 77Se resonance assignment of Sec-[N17A/F32T]-AnTx peptide. See DOI: 10.1039/c5sc03995a Click here for additional data file.

Ultrafast photoinduced electron transfer in face-to-face charge-transfer π-complexes of planar porphyrins and hexaazatriphenylene derivatives† †Electronic supplementary information (ESI) available: 1H, 13C NMR and MALDI-TOF mass spectra, cyclic voltammograms, fluorescence spectra, fluorescence titration spectra, 1H NMR titration, femtosecond laser-induced transient absorption spectral measurement data, and DFT data. See DOI: 10.1039/c4sc02787f Click here for additional data file.

Department of Chemistry, Faculty of Sc Yokohama, 223-8522, Japan. E-mail: hasob Department of Material and Life Science, University, ALCA, Japan Science and Tech 0871, Japan. E-mail: [email protected] Department of Applied Physics, Waseda U 169-8555, Japan. E-mail: takenobu@waseda † Electronic supplementary information MALDI-TOF mass spectra, cyclic vo uorescence titration spectra, H NMR tra...

Self-assembly of noble metal nanoparticles into sub-100 nm colloidosomes with collective optical and catalytic properties† †Electronic supplementary information (ESI) available: Additional experimental details, TEM images, FTIR spectra, size distributions, FDTD simulations, SERS analysis, electrochemical measurements, extension of the self-assembly approach to other metals and comparison of the FAOR results with those from the literature. See DOI: 10.1039/c7sc01841j

Centre for Materials Chemistry, Frontier In Jiaotong University, Xi’an, Shaanxi 710054 edu.cn School of Materials Science and Engine Shaanxi 710049, China Department of Chemistry, University of Cal † Electronic supplementary information ( details, TEM images, FTIR spectra, size d analysis, electrochemical measuremen approach to other metals and compariso the literature. See DOI: 10.1039/c7sc018...

Use of complementary nucleobase-containing synthetic polymers to prepare complex self-assembled morphologies in water† †Electronic supplementary information (ESI) available: Characterization of monomers, polymers and particles: NMR, SEC, TEM, SAXS, and DLS. See DOI: 10.1039/c6py00263c Click here for additional data file.

Amphiphilic nucleobase-containing block copolymers with poly(oligo(ethylene glycol) methyl ether methacrylate) as the hydrophilic block and nucleobase-containing blocks as the hydrophobic segments were successfully synthesized using RAFT polymerization and then self-assembled via solvent switch in aqueous solutions. Effects of the common solvent on the resultant morphologies of the adenine (A) ...

Molecular glues for manipulating enzymes: trypsin inhibition by benzamidine-conjugated molecular glues† †Electronic supplementary information (ESI) available: Synthesis of TEG–BA, Gluen–BA, mGluen–BA and Gluen–Ph; 1H NMR, 13C NMR, MALDI-TOF MS, electronic absorption, and CD spectra; zeta potential distributions; SLS plots; DLS histograms; and related experimental procedures. See DOI: 10.1039/c5sc00524h Click here for additional data file.

Water-soluble bioadhesive polymers bearing multiple guanidinium ion (Gu) pendants at their side-chain termini (Gluen–BA, n 1⁄4 10 and 29) that were conjugated with benzamidine (BA) as a trypsin inhibitor were developed. The Gluen–BA molecules are supposed to adhere to oxyanionic regions of the trypsin surface, even in buffer, via a multivalent Gu/oxyanion salt-bridge interaction, such that thei...